Reaction of 6-hydroxy-1,4,8,11-tetrathiacyclotetradecane (LH) with Cu(BF4)2 in THF yields [Cu(LH)](BF4)2; crystallisation of the complex from MeNO2/Et2O gives brown crystals of [Cu(LBF3)](BF4), the first example of alkoxide bridging between BF3 and a metal centre.
A novel alkoxide bridging motif between boron trifluoride and copper(II) in a crown thioether complex
L. R. Sutton, A. J. Blake, P. A. Cooke and M. Schröder, Chem. Commun., 2000, 563 DOI: 10.1039/A908778H
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