The synthesis and characterization of a novel mixed-valence MnGaPO phase is described; the 3D open-framework consists of discrete bioctahedra of Ga2O10(H2O) and GaO5 trigonal bipyramids, connected via MnIIIO4, MnIIO4 and PO4 tetrahedra to generate intersecting tunnels within which piperazinium cations reside.
K. Hsu and S. Wang, Chem. Commun., 2000, 135 DOI: 10.1039/A908334K
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