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Issue 1, 2000
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Self assembly of a novel water soluble iron(II) macrocyclic phosphine complex from tetrakis(hydroxymethyl)phosphonium sulfate and iron(II) ammonium sulfate: single crystal X-ray structure of the complex [Fe(H2O)2{RP(CH2N(CH2PR2)CH2)2PR}]SO4·4H2O (R = CH2OH)

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Abstract

The water soluble Fe(II) macrocyclic phosphine complex [Fe(H2O)2{RP(CH2N(CH2PR 2)CH2)2PR}]SO4·4H 2O (R = CH2OH) has been characterised by single crystal X-ray diffraction and is formed by a remarkable self-assembly reaction between iron(II) ammonium sulfate and tetrakis(hydroxymethyl)phosphonium sulfate (THPS).

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Publication details

The article was received on 18 Oct 1999, accepted on 06 Dec 1999 and first published on 06 Jan 2000


Article type: Communication
DOI: 10.1039/A908309J
Citation: Chem. Commun., 2000,0, 101-102

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    Self assembly of a novel water soluble iron(II) macrocyclic phosphine complex from tetrakis(hydroxymethyl)phosphonium sulfate and iron(II) ammonium sulfate: single crystal X-ray structure of the complex [Fe(H2O)2{RP(CH2N(CH2PR 2)CH2)2PR}]SO4·4H 2O (R = CH2OH)

    J. C. Jeffery, B. Odell, N. Stevens and R. E. Talbot, Chem. Commun., 2000, 0, 101
    DOI: 10.1039/A908309J

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