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Issue 22, 2000
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Synthesis based on cyclohexadienes. Part 34. A tandem cationic rearrangement–ene cyclisation route to 2-pupukeanone

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Abstract

A new strategy for the construction of the isotwistane skeleton is reported from easily available cyclohexadienes, which involves a one-pot cationic skeletal rearrangement and ene cyclisation of a bicyclo[2.2.2]octenone derivative and a cationic rearrangement of a tricyclo[5.3.0.04,8]decane to a [4.3.1.03,7]decane skeleton as the key steps in the synthesis of 2-pupukeanone.

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Publication details

The article was received on 27 Apr 2000, accepted on 04 Sep 2000 and first published on 19 Oct 2000


Article type: Paper
DOI: 10.1039/B003409F
J. Chem. Soc., Perkin Trans. 1, 2000, 3714-3718

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    Synthesis based on cyclohexadienes. Part 34. A tandem cationic rearrangement–ene cyclisation route to 2-pupukeanone

    P. J. Biju, K. Kaliappan, M. S. Laxmisha and G. S. R. Subba Rao, J. Chem. Soc., Perkin Trans. 1, 2000, 3714
    DOI: 10.1039/B003409F

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