Jump to main content
Jump to site search

Issue 24, 2000
Previous Article Next Article

Niobium–η-cyclopentadienyl compounds with imido and amido ligands derived from 2,6-dimethylaniline

Author affiliations

Abstract

The new niobium imido complex [Nb(η-C5H5){N(C6H3Me2-2,6)}Cl2] 1* has been prepared. Its reactions with anionic reagents lead to a series of alkyl and amido derivatives [Nb(η-C5H5){N(C6H3Me2-2,6)}MeCl] 2, [Nb(η-C5H5){N(C6H3Me2-2,6)}{NH(C6H3Me2-2,6)}Cl] 3, [Nb(η-C5H5){N(C6H3Me2-2,6)}{NH(C6H3Me2-2,6)}2] 4*, [Nb(η-C5H5)2{N(C6H3Me2-2,6)}Cl] 5, [Nb(η-C5H5)2{N(C6H3Me2-2,6)}Me] 6 and [Nb(η-C5H5){N(C6H3Me2-2,6)}{NH(C6H3Me2-2,6)}Me] 7*. Variable temperature NMR studies on the amido complexes 3, 4 and 7 are reported (* indicates the crystal structure has been determined).

Back to tab navigation

Supplementary files

Article information


Submitted
05 Sep 2000
Accepted
19 Oct 2000
First published
28 Nov 2000

J. Chem. Soc., Dalton Trans., 2000, 4555-4562
Article type
Paper

Niobium–η-cyclopentadienyl compounds with imido and amido ligands derived from 2,6-dimethylaniline

M. J. Humphries, M. L. H. Green, R. E. Douthwaite and L. H. Rees, J. Chem. Soc., Dalton Trans., 2000, 4555
DOI: 10.1039/B007178L

Search articles by author

Spotlight

Advertisements