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Issue 23, 2000
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Generation of aminoacyl radicals from 1-carbamoyl-1-methylcyclohexa-2,5- dienes: a new tin-free homolytic route to β- and γ-lactams

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Abstract

Radical induced homolyses of 1-carbamoyl-1-methylcyclohexa-2,5-dienes took place cleanly to yield aminoacyl radicals, with no competition from the alternative dissociation to methyl radicals: β- and γ-lactams were obtained from ring closures of suitably unsaturated model compounds.

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Publication details

The article was received on 13 Sep 2000, accepted on 03 Oct 2000 and first published on 09 Nov 2000


Article type: Communication
DOI: 10.1039/B007454N
Chem. Commun., 2000, 2327-2328

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    Generation of aminoacyl radicals from 1-carbamoyl-1-methylcyclohexa-2,5- dienes: a new tin-free homolytic route to β- and γ-lactams

    L. V. Jackson and J. C. Walton, Chem. Commun., 2000, 2327
    DOI: 10.1039/B007454N

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