Issue 23, 2000
From the journal:

Chemical Communications

Generation of aminoacyl radicals from 1-carbamoyl-1-methylcyclohexa-2,5- dienes: a new tin-free homolytic route to β- and γ-lactams

Leon V. Jacksona  and  John C. Walton*a  

* Corresponding authors

a University of St. Andrews, School of Chemistry, St. Andrews, Fife, UK
E-mail: jcw@st-and.ac.uk

Abstract

Radical induced homolyses of 1-carbamoyl-1-methylcyclohexa-2,5-dienes took place cleanly to yield aminoacyl radicals, with no competition from the alternative dissociation to methyl radicals: β- and γ-lactams were obtained from ring closures of suitably unsaturated model compounds.

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Article information

DOI
https://doi.org/10.1039/B007454N
Article type
Communication
Submitted
13 Sep 2000
Accepted
03 Oct 2000
First published
09 Nov 2000

Chem. Commun., 2000, 2327-2328

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Generation of aminoacyl radicals from 1-carbamoyl-1-methylcyclohexa-2,5- dienes: a new tin-free homolytic route to β- and γ-lactams

L. V. Jackson and J. C. Walton, Chem. Commun., 2000, 2327 DOI: 10.1039/B007454N

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