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Issue 22, 2000
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New insights into the endo–exo stereoselectivity of the intramolecular Diels-Alder reaction of 1,3,8-nonatrienesElectronic supplementary information (ESI) available: final optimised coordinates for stationary points in all transition structures. See http://www.rsc.org/suppdata/cc/b0/b006483l/

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Abstract

B3LYP/6-31G(d) theory predicts the experimental endoexo selectivity of intramolecular Diels-Alder reactions of C9-substituted 1,3,8-nonatrienes: the reactions are concerted but the transition structures are remarkably asynchronous.

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Article information


Submitted
08 Aug 2000
Accepted
27 Sep 2000
First published
01 Nov 2000

Chem. Commun., 2000, 2213-2214
Article type
Communication

New insights into the endo–exo stereoselectivity of the intramolecular Diels-Alder reaction of 1,3,8-nonatrienes

M. J. Lilly, M. N. Paddon-Row, M. S. Sherburn and C. I. Turner, Chem. Commun., 2000, 2213
DOI: 10.1039/B006483L

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