Jump to main content
Jump to site search

Issue 2, 2000
Previous Article Next Article

Synthesis and single crystal X-ray structure of the first cationic Pd(ii) complex of a tellurium-containing polyaza macrocycle: contrasting reactions of Pd(ii) and Pt(ii) with a 22-membered macrocyclic Schiff base

Abstract

The reaction of the tellurium containing macrocyclic Schiff base 1 with Pd(PhCN)2Cl2 and NH4PF6 gives the expected cationic complex [PdII1][PF6]2; by contrast the reaction of 1 with Pt(cod)Cl2 proceeds via novel transmetallation to yield an organoplatinum complex.

Back to tab navigation

Article information


Chem. Commun., 2000, 143-144
Article type
Paper

Synthesis and single crystal X-ray structure of the first cationic Pd(II) complex of a tellurium-containing polyaza macrocycle: contrasting reactions of Pd(II) and Pt(II) with a 22-membered macrocyclic Schiff base

S. C. Menon, A. Panda, H. B. Singh and R. J. Butcher, Chem. Commun., 2000, 143
DOI: 10.1039/A908683H

Social activity

Search articles by author

Spotlight

Advertisements