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Issue 19, 2000
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Intramolecular carbometalation of functionalized terminal alkynes via low-valent titanium complexes

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Abstract

Treatment of δ- and γ-functionalized monosubstituted alkynes with diisopropoxy(η2-propene)titanium induces an intramolecular cyclisation to afford the 4- and 5-membered cycloalkanols in good overall yields.

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Article information


Submitted
20 Jun 2000
Accepted
20 Jul 2000
First published
14 Sep 2000

Chem. Commun., 2000, 1849-1850
Article type
Communication

Intramolecular carbometalation of functionalized terminal alkynes via low-valent titanium complexes

N. Morlender-Vais, N. Solodovnikova and I. Marek, Chem. Commun., 2000, 1849
DOI: 10.1039/B005027J

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