1-Ethylpiperidine hypophosphite (1-EPHP) has been used in the key radical-cyclisation step in a 6-step synthesis of the phytotoxic metabolite alboatrin and its epimer from orcinol. The synthesis demonstrates that the stereochemistry of the structure initially proposed for alboatrin requires revision.
S. R. Graham, J. A. Murphy and A. R. Kennedy, J. Chem. Soc., Perkin Trans. 1, 1999, 3071 DOI: 10.1039/A907032J
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