Issue 24, 1999

Aminosilylation of aldehydes mediated by lithium perchlorate: novel method for synthesis of α-silylamines

Abstract

α-Silylated N,N-dialkylamines 7a–k were easily synthesized in good to excellent yields from aldehydes 1, (trimethylsilyl)dialkylamines 2, and phenyldimethylsilyllithium 4, diphenylmethylsilyllithium 5, or triphenylsilyllithium 6, in concentrated ethereal lithium perchlorate solution.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1999, 3709-3711

Aminosilylation of aldehydes mediated by lithium perchlorate: novel method for synthesis of α-silylamines

M. Reza Naimi-Jamal, M. M. Mojtahedi, J. Ipaktschi and M. R. Saidi, J. Chem. Soc., Perkin Trans. 1, 1999, 3709 DOI: 10.1039/A904498A

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