Issue 16, 1999

Photochemistry of chromones: photoreorganisation of 3-alkoxy-2-thienyl-4-oxo-4H-1-benzopyrans

Abstract

Photoirradiation of a methanolic solution of 3-alkoxy-2-thienyl-4-oxo-4H-1-benzopyrans with Pyrex filtered UV light leads to cyclised and cyclodehydrogenated angular products involving both thiophene and alkoxy groups. The reaction is initiated through H-abstraction. The product distribution depends upon the substituents on the thiophene ring.

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Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1999, 2391-2395

Photochemistry of chromones: photoreorganisation of 3-alkoxy-2-thienyl-4-oxo-4H-1-benzopyrans

S. C. Gupta, S. Sharma, A. Saini and S. N. Dhawan, J. Chem. Soc., Perkin Trans. 1, 1999, 2391 DOI: 10.1039/A901090D

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