Issue 2, 1999

Synthesis of novel diaryloxocyclopentanethiocarboxylates by electrochemical reduction of cinnamic acid thioesters

Abstract

The cathodic cyclic electrohydrodimerisation of a series of para-substituted (E )-methyl thiocinnamates in a polar aprotic solvent is presented. Only the all-trans (±)-3,4-diaryl-1-oxocyclopentane-2-thiocarboxylates are formed, as shown by assignments of 1H NMR coupling constants.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1999, 127-130

Synthesis of novel diaryloxocyclopentanethiocarboxylates by electrochemical reduction of cinnamic acid thioesters

J. Gruber and F. Ferraz Camilo, J. Chem. Soc., Perkin Trans. 1, 1999, 127 DOI: 10.1039/A808333I

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