Crystallographic data imply that intermolecular hypervalent interactions, “secondary bonds’', involving heavy p-block elements such as Bi(III), may form robust supramolecular synthons with many features in common with organic hydrogen bonds, including the ability to form polymeric networks in the solid state.
J. Starbuck, N. C. Norman and A. Guy Orpen, New J. Chem., 1999, 23, 969 DOI: 10.1039/A906352H
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