Issue 11, 1999
From the journal:

New Journal of Chemistry

First platinum clusters containing a direct Pt–Si bond: molecular structure of [Pt3{Si(OSiMe3)3}(µ-PPh2)3(PPh3)2] and electrochemical studies

Robert Bender,   Pierre Braunstein,   Salah-Eddine Bouaoud,   Naima Merabet,   Djamil Rouag,   Piero Zanello  and  Marco Fontani  

Abstract

The reaction of [Pt3Ph(µ-PPh2)3(PPh3)2] (1) with various silanes and siloxanes afforded the first platinum clusters containing a direct Pt–Si bond that could be characterized by X-ray diffraction, in the case of [Pt3{Si(OSiMe3)3}(µ-PPh2)3(PPh3)2] (2a): the redox properties of the 44-electron clusters 1 and [Pt3{Si(OMe)3}(µ-PPh2)3(PPh3)2] (2b) have been studied by cyclic voltammetry.

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Article information

DOI
https://doi.org/10.1039/A905840K
Article type
Paper

New J. Chem., 1999,23, 1045-1047

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First platinum clusters containing a direct Pt–Si bond: molecular structure of [Pt3{Si(OSiMe3)3}(µ-PPh2)3(PPh3)2] and electrochemical studies

R. Bender, P. Braunstein, S. Bouaoud, N. Merabet, D. Rouag, P. Zanello and M. Fontani, New J. Chem., 1999, 23, 1045 DOI: 10.1039/A905840K

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