The two main products from the reaction of a chiral Schiff-base proligand H2L with [NbIV(NEt2)4] are the amidoimido species [LNbV(NEt)(NEt2)] and the highly unusual [L′NbV(NEt2)2] in which a 1-ethylaminoethyl radical has undergone highly diastereoselective addition to one of the coordinated imine groups.
P. R. Woodman, C. J. Sanders, N. W. Alcock, P. B. Hitchcock and P. Scott, New J. Chem., 1999, 23, 815 DOI: 10.1039/A904579A
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