The marine natural products (±)-longamide (1), (±)-longamide B methyl ester (2), (±)-longamide B (3) and (±)-hanishin (4), each of which embodies a pyrroloketopiperazine core, have been synthesised in a concise fashion from pyrrole.
M. G. Banwell, A. M. Bray, A. C. Willis and D. J. Wong, New J. Chem., 1999, 23, 687 DOI: 10.1039/A903330K
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