Metal–arene complexes with suitable substituents on the π-bound arene represent a new class of organometallic building blocks for use in supramolecular chemistry. They provide a conceptually versatile avenue for construction of discrete assemblies and extended arrays, as is illustrated by the examples presented in which assembly occurs via hydrogen-bonded connections between carboxyl substituents.
R. Atencio, L. Brammer, S. Fang and F. Christopher Pigge, New J. Chem., 1999, 23, 461 DOI: 10.1039/A901925A
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