The intramolecular Pishchimuka rearrangement of 3-halopropyl-substituted thiophosphorylacetonitriles results in the corresponding 2-oxo-3-cyano-1,2-thiaphosphorinanes as a statistical mixture of two diastereomers, which transforms to an individual diastereomer with time; in benzene solution, the latter turns again into an equilibrium mixture of diastereomers.
I. L. Odinets, N. M. Vinogradova, O. I. Artyushin, P. V. Petrovskii, K. A. Lyssenko, M. Y. Antipin and T. A. Mastryukova, Mendeleev Commun., 1999, 9, 158 DOI: 10.1070/MC1999v009n04ABEH001141
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