New (1S,4S)-2,5-diazabicyclo[2.2.1]heptane derivatives synthesised by directed ortho metalation result in enantioselectivities of up to 78% e.e. when used as catalysts in the addition of diethylzinc to benzaldehyde.
U. Jordis, M. Kesselgruber, S. Nerdinger and K. Mereiter, Mendeleev Commun., 1999, 9, 147 DOI: 10.1070/MC1999v009n04ABEH001088
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