Issue 2, 1999
From the journal:

Journal of Materials Chemistry

Synthesis and crystal structure of MIL-14: a new layered fluoroaluminophosphate templated with tris(2-aminoethylamine): Al2(HPO4)3F2·H2PO4·N4C6H21

N. Simon,   T. Loiseau  and  G. Férey  

Abstract

MIL-14, formulated Al 2 (HPO 4 ) 3 F 2 ·H 2 PO 4 ·N 4 C 6 H 21 , is a new layered fluoroaluminophosphate obtained by hydrothermal synthesis using tris(2-aminoethyl)amine as a template. It crystallizes in the monoclinic space group P2 1 /c with a=13.154, b=9.518, c=17.889 Å, β=106.165° and Z=4. Its structure consists of an alternation along [100] direction of inorganic layers interleaved by amine phosphates. The structural unit of the inorganic layer contains five polyhedra: two aluminium octahedra and three HPO 4 tetrahedra. Strong hydrogen bonds ensured framework stability.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/A807303A
Article type
Paper

J. Mater. Chem., 1999,9, 585-589

Permissions

Request permissions

Synthesis and crystal structure of MIL-14: a new layered fluoroaluminophosphate templated with tris(2-aminoethylamine): Al2(HPO4)3F2·H2PO4·N4C6H21

N. Simon, T. Loiseau and G. Férey, J. Mater. Chem., 1999, 9, 585 DOI: 10.1039/A807303A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements