Methanolysis of the title substrates leads to different products depending on the conditions: in the presence of HCl both P–N bonds are broken yielding a non-cyclic phosphonic diester while the MeO– ion reacts selectively breaking the P–N(Ar) bond and yielding a cyclic, seven-membered phosphonic amidoester.
Z. He and T. A. Modro, J. Chem. Res. (S), 1999, 656 DOI: 10.1039/A904771I
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