A novel acylated triterpenoid saponin, designated pithecelloside, is isolated from the seeds of Pithecellobium dulce and characterised as 3-O-[α-L-arabinopyranosyl-(1 → 2)-α-L-arabinopyranosyl-(1 → 6)-β-D-glucopyranosyl]-21β-O-[(2′E)-6′-hydroxy-2′,6′-dimethylocta-2′,7′-dienoyl]acacic acid 1.
N. P. Sahu, K. Koike, Z. Jia, S. Banerjee, B. Achari and T. Nikaido, J. Chem. Res. (S), 1999, 558 DOI: 10.1039/A902637A
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