Acetylenic stannanes react with Cp2Zr(H)Cl (Cp=η5-C5H5) to give organozirconium(IV) complexes, which are trapped with arylsulfenyl chloride to afford (Z)-l-arylthio vinylstannanes.
X. Huang and P. Zhong, J. Chem. Res. (S), 1999, 290 DOI: 10.1039/A809042D
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