The reaction of carboxylic acids with propadiene or propyne catalysed by [Ru(µ-O2CH)(CO)2(PPh3)]2 affords isopropenyl esters via regioselective addition of the carboxylate to the central carbon atom of the allene.
C. Bruneau, M. Neveux-Duflos and P. H. Dixneuf, Green Chem., 1999, 1, 183 DOI: 10.1039/A903452H
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