A new polyoxo–alkoxo titanium cluster of the Keggin family: synthesis and characterization by X-ray diffraction and NMR spectroscopy
Abstract
The new [Ti17O24(OPri)20] cluster 1, that can be described as a non-charged lacunar super-Keggin complex, adopts a pseudo-D2d symmetry as established by X-ray diffraction and solution NMR studies.