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Issue 16, 1999
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Synthesis and structures of neutral and cationic 1-azaallylaluminium methyls

Abstract

The 1-azaallylaluminium compounds [[upper bond 1 start]Al{N(R)C(But)C[upper bond 1 end](H)R}{N(R)C(But)[double bond, length half m-dash]C(H)R}Me] (X-ray characterised), [upper bond 1 start]Al{N(R)C(But)C[upper bond 1 end](H)R}Me2, Al{N(R)C(Ph)[double bond, length half m-dash]C(H)R}Me2 3 and Al{N(R)C(Ph)[double bond, length half m-dash]C(H)R}2Me(thf ) were obtained from the appropriate methylaluminium chloride and 1-azaallyllithium; 3 with B(C6F5)3 gave [Al{N(R)C(Ph)[double bond, length half m-dash]C(H)R}Me(thf )(OEt2)][BMe(C6F5)3] (R = SiMe3).

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Supplementary files


Article type: Paper
DOI: 10.1039/A904138I
J. Chem. Soc., Dalton Trans., 1999, 2645-2646

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    Synthesis and structures of neutral and cationic 1-azaallylaluminium methyls

    L. Bourget, P. B. Hitchcock and M. F. Lappert, J. Chem. Soc., Dalton Trans., 1999, 2645
    DOI: 10.1039/A904138I

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