α-Fluorovinyldiphenylmethylsilane was synthesized in one step from 1,1-difluoroethylene; the TBAF-initiated reaction of the silane with carbonyl compounds smoothly proceeded to give the corresponding α-fluoroallylic alcohols in good yields.
T. Hanamoto, S. Harada, K. Shindo and M. Kondo, Chem. Commun., 1999, 2397 DOI: 10.1039/A907978E
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