Oxidation of [N(PPh3)2][Rh3(µ-NC6H4Me-p)2(CO)6] with [FeCp2]PF6 gives the novel hexarhodium compound [{Rh3(µ-NC6H4Me-p)2(CO)6}2], containing three nearly coplanar condensed metallic cycles forming a doubly-spiked square, by dimersisation of the trinuclear imidocomplex through the formation of unsupported metal–metal bonds.
C. Tejel, M. Bordonaba, M. A. Ciriano, F. J. Lahoz and L. A. Oro, Chem. Commun., 1999, 2387 DOI: 10.1039/A907853C
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