The novel ortho-metallated complex (R,R)-di-µ-chlorobis{9-[(1-dimethylamino)ethyl]-10-phenanthrenyl-C,N}dipalladium has been prepared and found to be a significantly better catalyst than its phenyl and naphthylamine analogues for the asymmetric Claisen rearrangement of a non-activated allyl imidate.
P. Leung, K. Ng, Y. Li, A. J. P. White and D. J. Williams, Chem. Commun., 1999, 2435 DOI: 10.1039/A907617D
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