Porphyrins fused with bicyclo[2.2.2]octene frameworks are prepared; the bicyclo[2.2.2] units rigidify the porphyrin ring to maintain planar conformations in solution.
S. Ito, T. Murashima, N. Ono and H. Uno, Chem. Commun., 1999, 2275 DOI: 10.1039/A907460K
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