The reaction between [NiMe{(Ph2PCH2CH2)2PPh}]+ and anhydrous HCl (in MeCN) involves initial protonation of nickel to form [Ni(H)Me{(Ph2PCH2CH2)2PPh}]2+, but methane is not produced until after additional, direct protonation of the methyl group.
R. A. Henderson and K. E. Oglieve, Chem. Commun., 1999, 2271 DOI: 10.1039/A907080J
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