Control of the microarchitecture in a metallo-supramolecular double-helical array results from inter-strand edge–face π-stacking interactions which pull the ligand strands together thereby creating two distinct helical grooves (major and minor).
M. J. Hannon, C. L. Painting and N. W. Alcock, Chem. Commun., 1999, 2023 DOI: 10.1039/A905795A
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