Issue 18, 1999
From the journal:

Chemical Communications

Hexahomotrioxacalix[3]arene: a scaffold for a C3-symmetric phosphine ligand that traps a hydrido-rhodium fragment inside a molecular funnel

Cedric B. Dieleman,   Dominique Matt,   Ion Neda,   Reinhard Schmutzler,   Anthony Harriman  and  Reza Yaftian  

Abstract

Stereoselectivity around an H–Rh–CO fragment has been realized by reaction of the hexahomotrioxacalix[3]arene-derived triphosphine 4 with [Rh(acac)(CO)2]; the resultant trigonal bipyramidal complex has the Rh–H bond directed inside the cavity.

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DOI
https://doi.org/10.1039/A905677G
Article type
Paper

Chem. Commun., 1999, 1911-1912

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Hexahomotrioxacalix[3]arene: a scaffold for a C3-symmetric phosphine ligand that traps a hydrido-rhodium fragment inside a molecular funnel

C. B. Dieleman, D. Matt, I. Neda, R. Schmutzler, A. Harriman and R. Yaftian, Chem. Commun., 1999, 1911 DOI: 10.1039/A905677G

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