Macropolyhedral boron-containing cluster chemistry. The [SB17H19]– anion: a nido-ten-vertex : arachno-ten-vertex cluster architecture and the first single-sulfur macropolyhedral thiaborane
Abstract
Reaction of syn-B18H22 with metabisulfite gives a good yield of the first single-sulfur macropolyhedral thiaborane, the [SB17H19]– anion, which exhibits the unusual arachno–nido two-borons-in-common cluster fusion mode.
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