Continuing uncertainty about pathways and consequences of the photolability of aryl sulfonamides is partly resolved by the results of comprehensive product analysis in the photolysis of aqueous N-tosylglycine, which indicate that intramolecular electron or hydrogen transfer (according to conditions) promote the widely reported S–N cleavage and reveal the nature of subsequent and competing processes.
R. R. Hill, G. E. Jeffs, D. R. Roberts and S. A. Wood, Chem. Commun., 1999, 1735 DOI: 10.1039/A905358A
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