Baylis–Hillman adducts derived from enantiopure 1-alkenyl- or alkynyl-4-oxoazetidine-2-carbaldehydes are used for the stereoselective and divergent preparation of highly functionalised β-lactams fused to medium rings through novel, chemocontrolled tandem radical addition–cyclization sequences.
B. Alcaide, P. Almendros and C. Aragoncillo, Chem. Commun., 1999, 1913 DOI: 10.1039/A905017E
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