The in situ alcohol oxidation–Wittig reaction using manganese dioxide as the oxidant has been applied to semi-activated and, for the first time, unactivated alcohols to furnish the corresponding α,β-unsaturated esters.
L. Blackburn, X. Wei and R. J. K. Taylor, Chem. Commun., 1999, 1337 DOI: 10.1039/A903980E
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