Issue 24, 1999

Nickel mediated sulfur–selenium and sulfur–sulfur bond formation

Abstract

Electrophilic addition of the PhSeCl to a nickel dithiolate yields S,S′-bis(phenylselenenyl-N,N′-bis(mercaptoethyl)-1,5-diazacyclooctane nickel(II) dichloride and a dimeric, intermolecular bis-disulfide which results from ligand oxidation.

Article information

Article type
Paper

Chem. Commun., 1999, 2473-2474

Nickel mediated sulfur–selenium and sulfur–sulfur bond formation

C. Lai, J. H. Reibenspies and M. Y. Darensbourg, Chem. Commun., 1999, 2473 DOI: 10.1039/A903973B

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