[Cp*Co(CO)2] in the presence of PEt3 and MeI catalyses the carbonylation of methanol with initial rates up to 44 mol dm–3 h–1 before decaying to a second catalytic phase with rates of 3 mol dm–3 h–1; [CoI(CO)2(PEt3)2], which is trigonal bipyramidal with axial PEt3 ligands, has been isolated from the final reaction solution.
A. C. Marr, A. C. Benyei, P. Lightfoot, D. J. Cole-Hamilton and E. J. Ditzel, Chem. Commun., 1999, 1379 DOI: 10.1039/A903169C
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