Issue 16, 1999
From the journal:

Chemical Communications

A novel two-electron mixed-valence Ir(II)–Ir(0) complex

Alan F. Heyduk  and  Daniel G. Nocera  

Abstract

An IrII–Ir0 mixed-valence complex, Ir2{MeN[P(OEtF3)2]2}3Cl2 (OEtF3 = OCH2CF3), has been prepared by treatment of Ir2Cl2(cod)2 with 3 equiv. of MeN[P(OEtF3)2]2; donor ligands (CNBut and PEt3) add to the binuclear core, which provides a novel platform for the multielectron activation of small molecule substrates.

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Article information

DOI
https://doi.org/10.1039/A902487E
Article type
Paper

Chem. Commun., 1999, 1519-1520

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A novel two-electron mixed-valence Ir(II)–Ir(0) complex

A. F. Heyduk and D. G. Nocera, Chem. Commun., 1999, 1519 DOI: 10.1039/A902487E

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