Issue 15, 1999

Catalytic radical acetylation of adamantanes with biacetyl by a cobalt salt under atmospheric dioxygen

Abstract

Exposure of a mixture of adamantane and biacetyl under O2 in the presence of Co(OAc)2 (0.1 mol%) in AcOH led to 1-acetyladamantane (47%) and 1,3-diacetyladamantane (20%) as major products along with small amounts of adamantan-1-ol (4%) and adamantan-2-one (3%).

Article information

Article type
Paper

Chem. Commun., 1999, 1421-1422

Catalytic radical acetylation of adamantanes with biacetyl by a cobalt salt under atmospheric dioxygen

A. Kishi, S. Kato, S. Sakaguchi and Y. Ishii, Chem. Commun., 1999, 1421 DOI: 10.1039/A902384D

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