SCHEDULED MAINTENANCE
The synthesis of 4,4′-bis(dialkylaminostyryl)-6,6′-dimethyl-2,2′-bipyridine ligands is described; the corresponding tetrahedral bis(bipyridyl) copper(I) complexes have been prepared, and their second-order nonlinear optical properties determined by harmonic light scattering (HLS) at 1.34 µm; these new octupolar complexes exhibit large molecular hyperpolarisabilities β.
T. Renouard, H. Le Bozec, S. Brasselet, I. Ledoux and J. Zyss, Chem. Commun., 1999, 871 DOI: 10.1039/A901972C
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