Issue 10, 1999

Unusual cyclopropanol formation from a β-silyl aldehyde

Abstract

The hemiacetals 15 and 18 gave cyclopropanols 17 and 20 when treated with NaH in DMSO, showing that the silyl group has enhanced electrofugal powers because of the participation of the oxyanion.

Article information

Article type
Paper

Chem. Commun., 1999, 923-924

Unusual cyclopropanol formation from a β-silyl aldehyde

I. Fleming and A. K. Mandal, Chem. Commun., 1999, 923 DOI: 10.1039/A901920K

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