Issue 9, 1999
From the journal:

Chemical Communications

Metallation-induced migration of phosphorus from nitrogen to carbon in 1-oxo-2,8-diphenyl-2,5,8-triaza-1λ5-phosphabicyclo[3.3.0]octane: unusual bonding parameters of the double migration product

Zhengjie He,   Tomasz A. Modro,   Petrus H. Van Rooyen  and  Susan A. Bourne  

Abstract

The title compound undergoes lithiation-induced rearrangement, first to a bicyclic phosphonic diamide, and next to a bicyclic phosphinic amide; for the latter product an unusually long phosphoryl bond was observed.

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Article information

DOI
https://doi.org/10.1039/A901877H
Article type
Paper

Chem. Commun., 1999, 853-854

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Metallation-induced migration of phosphorus from nitrogen to carbon in 1-oxo-2,8-diphenyl-2,5,8-triaza-1λ5-phosphabicyclo[3.3.0]octane: unusual bonding parameters of the double migration product

Z. He, T. A. Modro, P. H. Van Rooyen and S. A. Bourne, Chem. Commun., 1999, 853 DOI: 10.1039/A901877H

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