A new approach for the epoxidation of alkenes using O2 without any metal catalyst was developed; a variety of alkenes were epoxidized in a regio- and stereoselective manner with O2 in the presence of benzhydrol catalyzed by N-hydroxyphthalimide and hexafluoroacetone.
T. Iwahama, S. Sakaguchi and Y. Ishii, Chem. Commun., 1999, 727 DOI: 10.1039/A901615E
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