Issue 11, 1999
From the journal:

Chemical Communications

A new combination of donor and acceptor: bis(η6-benzene)chromium and hexafluorobenzene form a charge-transfer stacked crystal

Catherine J. Aspley,   Clive Boxwell,   Maria L. Buil,   Catherine L. Higgitt,   Robin N. Perutz  and  Conor Long  

Abstract

Bis(η6-benzene)chromium reacts with hexafluorobenzene to yield a red charge-transfer complex [Cr(η6-C6H6)2•C6F6] which contains stacks of alternating donor and acceptor molecules with close inter- and intrastack contacts; in addition to the charge-transfer complex, formation of [Cr(η6-C6H6)2]+ is demonstrated by EPR and IR spectroscopy.

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Article information

DOI
https://doi.org/10.1039/A900919A
Article type
Paper

Chem. Commun., 1999, 1027-1028

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A new combination of donor and acceptor: bis(η6-benzene)chromium and hexafluorobenzene form a charge-transfer stacked crystal

C. J. Aspley, C. Boxwell, M. L. Buil, C. L. Higgitt, R. N. Perutz and C. Long, Chem. Commun., 1999, 1027 DOI: 10.1039/A900919A

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