The condensation of a dipyrromethane with ferrocene aldehyde leads to a single atropisomer of α,α-5,15-bis(ferrocenyl)-2,8,12,18-tetrabutyl-3,7,13,17-tetramethylporphyrin 1; electrochemistry of 1 and Ni-1 reveals two consecutive ferrocene-based one-electron oxidation waves, which are separated by 0.19 and 0.41 V, respectively.
A. K. Burrell, W. M. Campbell, G. B. Jameson, D. L. Officer, P. D. W. Boyd, Z. Zhao, P. A. Cocks and K. C. Gordon, Chem. Commun., 1999, 637 DOI: 10.1039/A900691E
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