Issue 5, 1999
From the journal:

Chemical Communications

Phospha-alkyne hydro-osmiation: synthesis of [Os{κ1P,κ1P′-P[double bond, length half m-dash]CRP([double bond, length half m-dash]CHR)}Cl(CO)(PPh3)2] (R = CMe3)

Anthony F. Hill,   James D. E. T. Wilton-Ely  and  Cameron Jones  

Abstract

The reaction of [OsHCl(CO)(PPh3)2(BTD)] (BTD = 2,1,3-benzothiadiazole) with P[triple bond, length half m-dash]CCMe3 provides the novel complex [Os{κ1P,κ1P′-P[double bond, length half m-dash]CRP([double bond, length half m-dash]CHR)Cl(CO)(PPh3)2] (R = CMe3) which features both phospha-alkenyl and phospha-alkene donors within the same metallacycle.

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Article information

DOI
https://doi.org/10.1039/A900257J
Article type
Paper

Chem. Commun., 1999, 451-452

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Phospha-alkyne hydro-osmiation: synthesis of [Os{κ1P,κ1P′-P[double bond, length half m-dash]CRP([double bond, length half m-dash]CHR)}Cl(CO)(PPh3)2] (R = CMe3)

A. F. Hill, J. D. E. T. Wilton-Ely and C. Jones, Chem. Commun., 1999, 451 DOI: 10.1039/A900257J

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