Issue 10, 1999

Hydrazinolysis of Fischer-type oxacarbenes made efficient: a new and easy entry to alkyl and aryl hydrazinocarbene complexes

Abstract

Hydrazinolysis of the pentacarbonyl[alkyl- or aryl-(methoxy)carbene] complexes of W0 and Cr0 with both 1,1- and 1,2-disubstituted hydrazines affords the corresponding new hydrazinocarbenes 15–18, 21 and 22, and the presence of LiCl in the reaction medium greatly increases their yields.

Additions and corrections

Article information

Article type
Paper

Chem. Commun., 1999, 925-926

Hydrazinolysis of Fischer-type oxacarbenes made efficient: a new and easy entry to alkyl and aryl hydrazinocarbene complexes

E. Licandro, S. Maiorana, A. Papagni, D. Perdicchia and R. Manzotti, Chem. Commun., 1999, 925 DOI: 10.1039/A900166B

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